Adsorption of methane on an MOF-199 organometallic framework structure at high pressures in the range of supercritical temperatures
- Авторы: Tsivadze A.Y.1, Aksyutin O.E.2, Ishkov A.G.2, Fomkin A.A.1, Men’shchikov I.E.1, Pribylov A.A.1, Isaeva V.I.3, Kustov L.M.3, Shkolin A.V.1, Strizhenov E.M.1
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Учреждения:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- OJSC Gazprom
- Zelinskii Institute of Organic Chemistry
- Выпуск: Том 52, № 1 (2016)
- Страницы: 24-29
- Раздел: Physicochemical Processes at the Interfaces
- URL: https://journals.rcsi.science/2070-2051/article/view/202494
- DOI: https://doi.org/10.1134/S2070205116010263
- ID: 202494
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Аннотация
Synthesis of an adsorbent based on an organometallic framework of the MOF-199 type is performed. The Dubinin–Radushkevich equation is used to calculate the structure–energy characteristics of adsorbents on the basis of data on nitrogen adsorption at 77 K as per benzene. Methane adsorption is studied on the obtained MOF-199 adsorbent, and adsorption isosteres are plotted. The capacitive characteristics of the adsorption system for methane storage with the synthesized adsorbent are determined. Differential molar isosteric and integral adsorption heats are calculated.
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Об авторах
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Россия, Leninskii pr. 31, bldg 4, Moscow, 117997
O. Aksyutin
OJSC Gazprom
Email: i.menschikov@mail.ru
Россия, Moscow
A. Ishkov
OJSC Gazprom
Email: i.menschikov@mail.ru
Россия, Moscow
A. Fomkin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Россия, Leninskii pr. 31, bldg 4, Moscow, 117997
I. Men’shchikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Автор, ответственный за переписку.
Email: i.menschikov@mail.ru
Россия, Leninskii pr. 31, bldg 4, Moscow, 117997
A. Pribylov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Россия, Leninskii pr. 31, bldg 4, Moscow, 117997
V. Isaeva
Zelinskii Institute of Organic Chemistry
Email: i.menschikov@mail.ru
Россия, Moscow, 119334
L. Kustov
Zelinskii Institute of Organic Chemistry
Email: i.menschikov@mail.ru
Россия, Moscow, 119334
A. Shkolin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Россия, Leninskii pr. 31, bldg 4, Moscow, 117997
E. Strizhenov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Россия, Leninskii pr. 31, bldg 4, Moscow, 117997
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