Email this article Adsorption of methane on an MOF-199 organometallic framework structure at high pressures in the range of supercritical temperatures
- Authors: Tsivadze A.Y.1, Aksyutin O.E.2, Ishkov A.G.2, Fomkin A.A.1, Men’shchikov I.E.1, Pribylov A.A.1, Isaeva V.I.3, Kustov L.M.3, Shkolin A.V.1, Strizhenov E.M.1
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- OJSC Gazprom
- Zelinskii Institute of Organic Chemistry
- Issue: Vol 52, No 1 (2016)
- Pages: 24-29
- Section: Physicochemical Processes at the Interfaces
- URL: https://journals.rcsi.science/2070-2051/article/view/202494
- DOI: https://doi.org/10.1134/S2070205116010263
- ID: 202494
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Abstract
Synthesis of an adsorbent based on an organometallic framework of the MOF-199 type is performed. The Dubinin–Radushkevich equation is used to calculate the structure–energy characteristics of adsorbents on the basis of data on nitrogen adsorption at 77 K as per benzene. Methane adsorption is studied on the obtained MOF-199 adsorbent, and adsorption isosteres are plotted. The capacitive characteristics of the adsorption system for methane storage with the synthesized adsorbent are determined. Differential molar isosteric and integral adsorption heats are calculated.
About the authors
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Russian Federation, Leninskii pr. 31, bldg 4, Moscow, 117997
O. E. Aksyutin
OJSC Gazprom
Email: i.menschikov@mail.ru
Russian Federation, Moscow
A. G. Ishkov
OJSC Gazprom
Email: i.menschikov@mail.ru
Russian Federation, Moscow
A. A. Fomkin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Russian Federation, Leninskii pr. 31, bldg 4, Moscow, 117997
I. E. Men’shchikov
Frumkin Institute of Physical Chemistry and Electrochemistry
Author for correspondence.
Email: i.menschikov@mail.ru
Russian Federation, Leninskii pr. 31, bldg 4, Moscow, 117997
A. A. Pribylov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Russian Federation, Leninskii pr. 31, bldg 4, Moscow, 117997
V. I. Isaeva
Zelinskii Institute of Organic Chemistry
Email: i.menschikov@mail.ru
Russian Federation, Moscow, 119334
L. M. Kustov
Zelinskii Institute of Organic Chemistry
Email: i.menschikov@mail.ru
Russian Federation, Moscow, 119334
A. V. Shkolin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Russian Federation, Leninskii pr. 31, bldg 4, Moscow, 117997
E. M. Strizhenov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
Russian Federation, Leninskii pr. 31, bldg 4, Moscow, 117997
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