Adsorption of methane on an MOF-199 organometallic framework structure at high pressures in the range of supercritical temperatures
- 作者: Tsivadze A.Y.1, Aksyutin O.E.2, Ishkov A.G.2, Fomkin A.A.1, Men’shchikov I.E.1, Pribylov A.A.1, Isaeva V.I.3, Kustov L.M.3, Shkolin A.V.1, Strizhenov E.M.1
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隶属关系:
- Frumkin Institute of Physical Chemistry and Electrochemistry
- OJSC Gazprom
- Zelinskii Institute of Organic Chemistry
- 期: 卷 52, 编号 1 (2016)
- 页面: 24-29
- 栏目: Physicochemical Processes at the Interfaces
- URL: https://journals.rcsi.science/2070-2051/article/view/202494
- DOI: https://doi.org/10.1134/S2070205116010263
- ID: 202494
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详细
Synthesis of an adsorbent based on an organometallic framework of the MOF-199 type is performed. The Dubinin–Radushkevich equation is used to calculate the structure–energy characteristics of adsorbents on the basis of data on nitrogen adsorption at 77 K as per benzene. Methane adsorption is studied on the obtained MOF-199 adsorbent, and adsorption isosteres are plotted. The capacitive characteristics of the adsorption system for methane storage with the synthesized adsorbent are determined. Differential molar isosteric and integral adsorption heats are calculated.
作者简介
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997
O. Aksyutin
OJSC Gazprom
Email: i.menschikov@mail.ru
俄罗斯联邦, Moscow
A. Ishkov
OJSC Gazprom
Email: i.menschikov@mail.ru
俄罗斯联邦, Moscow
A. Fomkin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997
I. Men’shchikov
Frumkin Institute of Physical Chemistry and Electrochemistry
编辑信件的主要联系方式.
Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997
A. Pribylov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997
V. Isaeva
Zelinskii Institute of Organic Chemistry
Email: i.menschikov@mail.ru
俄罗斯联邦, Moscow, 119334
L. Kustov
Zelinskii Institute of Organic Chemistry
Email: i.menschikov@mail.ru
俄罗斯联邦, Moscow, 119334
A. Shkolin
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997
E. Strizhenov
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997
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