Adsorption of methane on an MOF-199 organometallic framework structure at high pressures in the range of supercritical temperatures


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Synthesis of an adsorbent based on an organometallic framework of the MOF-199 type is performed. The Dubinin–Radushkevich equation is used to calculate the structure–energy characteristics of adsorbents on the basis of data on nitrogen adsorption at 77 K as per benzene. Methane adsorption is studied on the obtained MOF-199 adsorbent, and adsorption isosteres are plotted. The capacitive characteristics of the adsorption system for methane storage with the synthesized adsorbent are determined. Differential molar isosteric and integral adsorption heats are calculated.

作者简介

A. Tsivadze

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997

O. Aksyutin

OJSC Gazprom

Email: i.menschikov@mail.ru
俄罗斯联邦, Moscow

A. Ishkov

OJSC Gazprom

Email: i.menschikov@mail.ru
俄罗斯联邦, Moscow

A. Fomkin

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997

I. Men’shchikov

Frumkin Institute of Physical Chemistry and Electrochemistry

编辑信件的主要联系方式.
Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997

A. Pribylov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997

V. Isaeva

Zelinskii Institute of Organic Chemistry

Email: i.menschikov@mail.ru
俄罗斯联邦, Moscow, 119334

L. Kustov

Zelinskii Institute of Organic Chemistry

Email: i.menschikov@mail.ru
俄罗斯联邦, Moscow, 119334

A. Shkolin

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997

E. Strizhenov

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: i.menschikov@mail.ru
俄罗斯联邦, Leninskii pr. 31, bldg 4, Moscow, 117997

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