Synthesis of Decaborane by the Reaction of Sodium Undecaborate with Mild Organic Oxidants

P. P. Belov; P. A. Storozhenko; N. S. Voloshina; M. G. Kuznetsova

doi:10.1134/S107042721711012X

Synthesis of Decaborane by the Reaction of Sodium Undecaborate with Mild Organic Oxidants

Authors: Belov P.P.¹, Storozhenko P.A.¹, Voloshina N.S.¹, Kuznetsova M.G.¹
Affiliations:
1. State Research Institute of Chemistry and Technology of Organoelement Compounds
Issue: Vol 90, No 11 (2017)
Pages: 1804-1809
Section: Specific Technological Processes
URL: https://journals.rcsi.science/1070-4272/article/view/215387
DOI: https://doi.org/10.1134/S107042721711012X
ID: 215387

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Abstract

New organic oxidants (aldehydes and ketones) allowing efficient synthesis of decaborane in a high yield via intermediate alkali metal salt were found. The sodium undecaborate oxidation process was refined, and new reaction stoichiometry was suggested.