Synthesis of Decaborane by the Reaction of Sodium Undecaborate with Mild Organic Oxidants


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New organic oxidants (aldehydes and ketones) allowing efficient synthesis of decaborane in a high yield via intermediate alkali metal salt were found. The sodium undecaborate oxidation process was refined, and new reaction stoichiometry was suggested.

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P. Belov

State Research Institute of Chemistry and Technology of Organoelement Compounds

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Email: ppbeloff@mail.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 111123

P. Storozhenko

State Research Institute of Chemistry and Technology of Organoelement Compounds

Email: ppbeloff@mail.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 111123

N. Voloshina

State Research Institute of Chemistry and Technology of Organoelement Compounds

Email: ppbeloff@mail.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 111123

M. Kuznetsova

State Research Institute of Chemistry and Technology of Organoelement Compounds

Email: ppbeloff@mail.ru
俄罗斯联邦, sh. Entuziastov 38, Moscow, 111123

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