Synthesis of Decaborane by the Reaction of Sodium Undecaborate with Mild Organic Oxidants
- Autores: Belov P.P.1, Storozhenko P.A.1, Voloshina N.S.1, Kuznetsova M.G.1
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Afiliações:
- State Research Institute of Chemistry and Technology of Organoelement Compounds
- Edição: Volume 90, Nº 11 (2017)
- Páginas: 1804-1809
- Seção: Specific Technological Processes
- URL: https://journals.rcsi.science/1070-4272/article/view/215387
- DOI: https://doi.org/10.1134/S107042721711012X
- ID: 215387
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Resumo
New organic oxidants (aldehydes and ketones) allowing efficient synthesis of decaborane in a high yield via intermediate alkali metal salt were found. The sodium undecaborate oxidation process was refined, and new reaction stoichiometry was suggested.
Sobre autores
P. Belov
State Research Institute of Chemistry and Technology of Organoelement Compounds
Autor responsável pela correspondência
Email: ppbeloff@mail.ru
Rússia, sh. Entuziastov 38, Moscow, 111123
P. Storozhenko
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: ppbeloff@mail.ru
Rússia, sh. Entuziastov 38, Moscow, 111123
N. Voloshina
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: ppbeloff@mail.ru
Rússia, sh. Entuziastov 38, Moscow, 111123
M. Kuznetsova
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: ppbeloff@mail.ru
Rússia, sh. Entuziastov 38, Moscow, 111123
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