Synthesis of Decaborane by the Reaction of Sodium Undecaborate with Mild Organic Oxidants
- Authors: Belov P.P.1, Storozhenko P.A.1, Voloshina N.S.1, Kuznetsova M.G.1
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Affiliations:
- State Research Institute of Chemistry and Technology of Organoelement Compounds
- Issue: Vol 90, No 11 (2017)
- Pages: 1804-1809
- Section: Specific Technological Processes
- URL: https://journals.rcsi.science/1070-4272/article/view/215387
- DOI: https://doi.org/10.1134/S107042721711012X
- ID: 215387
Cite item
Abstract
New organic oxidants (aldehydes and ketones) allowing efficient synthesis of decaborane in a high yield via intermediate alkali metal salt were found. The sodium undecaborate oxidation process was refined, and new reaction stoichiometry was suggested.
About the authors
P. P. Belov
State Research Institute of Chemistry and Technology of Organoelement Compounds
Author for correspondence.
Email: ppbeloff@mail.ru
Russian Federation, sh. Entuziastov 38, Moscow, 111123
P. A. Storozhenko
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: ppbeloff@mail.ru
Russian Federation, sh. Entuziastov 38, Moscow, 111123
N. S. Voloshina
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: ppbeloff@mail.ru
Russian Federation, sh. Entuziastov 38, Moscow, 111123
M. G. Kuznetsova
State Research Institute of Chemistry and Technology of Organoelement Compounds
Email: ppbeloff@mail.ru
Russian Federation, sh. Entuziastov 38, Moscow, 111123
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