Acid—Base Interactions and Complexation of β-Substituted Porphyrazines with Magnesium Salts in Proton-Acceptor Media
- 作者: Petrov O.1
-
隶属关系:
- Ivanovo State University of Chemistry and Technology
- 期: 卷 89, 编号 11 (2019)
- 页面: 2251-2257
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/223164
- DOI: https://doi.org/10.1134/S107036321911015X
- ID: 223164
如何引用文章
详细
Analysis of the complexing ability of β-substituted porphyrazines toward magnesium acetate and magnesium acetylacetonate in the systems dimethyl sulfoxide-benzene (chlorobenzene) and nitrogen base-benzene has shown that acid-base interaction is the key factor affecting the complexation of porphyrazines with magnesium salts in proton-acceptor media with different basicities. The mechanism of formation of porphyrazine magnesium complexes and the structure and stability of acid-base complexes of porphyrazines with dimethyl sulfoxide and nitrogen bases in benzene (chlorobenzene) are discussed.
作者简介
O. Petrov
Ivanovo State University of Chemistry and Technology
编辑信件的主要联系方式.
Email: poa@isuct.ru
俄罗斯联邦, Ivanovo, 153000
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