Interaction of Titanium, Zirconium and Hafnium Metallocene Dichlorides with Styrene and Methyl Methacrylate in the Media of Different Polarity
- 作者: Puzin Y.1, Zakharova E.2, Puzin P.1, Mastobaev B.1, Pimenov A.3
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隶属关系:
- Ufa State Petroleum Technological University
- Ufa Institute of Chemistry
- UGMK-Holding Ltd
- 期: 卷 89, 编号 4 (2019)
- 页面: 747-752
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222863
- DOI: https://doi.org/10.1134/S1070363219040182
- ID: 222863
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详细
The UV spectral study of the interaction of titanium, zirconium, and hafnium metallocene dichlorides with styrene or methyl methacrylate in the media of different polarity (carbon tetrachloride and ethanol) has been carried out using the isomolar series method. The formation of weak intermediate complexes has been shown, the solvent polarity significantly affecting the process of their formation. It has been found for the first time that charge-transfer complexes between metallocene dichlorides and styrene are formed only in polar solvent (ethanol). Possible structures of intermediate complexes have been proposed.
作者简介
Yu. Puzin
Ufa State Petroleum Technological University
编辑信件的主要联系方式.
Email: ppuziny@mail.ru
俄罗斯联邦, ul. Kosmonavtov 1, Ufa, 450062
E. Zakharova
Ufa Institute of Chemistry
Email: ppuziny@mail.ru
俄罗斯联邦, Ufa
P. Puzin
Ufa State Petroleum Technological University
Email: ppuziny@mail.ru
俄罗斯联邦, ul. Kosmonavtov 1, Ufa, 450062
B. Mastobaev
Ufa State Petroleum Technological University
Email: ppuziny@mail.ru
俄罗斯联邦, ul. Kosmonavtov 1, Ufa, 450062
A. Pimenov
UGMK-Holding Ltd
Email: ppuziny@mail.ru
俄罗斯联邦, Verkhnyaya Pyshma