Kinetic Stability of Tetra(1,2,5-selenodiazolo)porphyrazine in the Nitrogen-Containing Base-Dimethyl Sulfoxide System
- 作者: Petrov O.1, Kiselev A.2, Teletskii Z.1, Belyaeva A.1
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隶属关系:
- Ivanovo State University of Chemistry and Technology
- Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
- 期: 卷 89, 编号 3 (2019)
- 页面: 429-433
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222785
- DOI: https://doi.org/10.1134/S1070363219030101
- ID: 222785
如何引用文章
详细
The behavior of tetra(1,2,5-selenodiazolo)porphyrazine in DMSO and in the DMSO-base (pyridine, 2-methyl-pyridine, morpholine, and piperidine) systems has been studied. It has been shown that the π-chromophore system of the macrocycle is decomposed with time in strongly basic media. The proton-transfer complex H2PA(SeN2)4·2DMSO formed in DMSO has been less kinetically stable in the presence of morpholine (piperidine) than the H2PA(SN2)4·2DMSO complex.
作者简介
O. Petrov
Ivanovo State University of Chemistry and Technology
编辑信件的主要联系方式.
Email: poa@isuct.ru
俄罗斯联邦, prosp. Sheremetevskii 7, Ivanovo, 153000
A. Kiselev
Krestov Institute of Solution Chemistry of the Russian Academy of Sciences
Email: poa@isuct.ru
俄罗斯联邦, Ivanovo
Z. Teletskii
Ivanovo State University of Chemistry and Technology
Email: poa@isuct.ru
俄罗斯联邦, prosp. Sheremetevskii 7, Ivanovo, 153000
A. Belyaeva
Ivanovo State University of Chemistry and Technology
Email: poa@isuct.ru
俄罗斯联邦, prosp. Sheremetevskii 7, Ivanovo, 153000
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