Phosphorylation of Acetylaminophenols with Secondary Phosphine Chalcogenides: Synthesis of  O -(Acetylamino)phenyl Chalcogenophosphinates

P. A. Volkov; N. I. Ivanova; A. A. Telezhkin; K. O. Khrapova; L. I. Larina; N. K. Gusarova; B. A. Trofimov

doi:10.1134/S1070363219010109

Phosphorylation of Acetylaminophenols with Secondary Phosphine Chalcogenides: Synthesis of O-(Acetylamino)phenyl Chalcogenophosphinates

作者: Volkov P.¹, Ivanova N.¹, Telezhkin A.¹, Khrapova K.¹, Larina L.¹, Gusarova N.¹, Trofimov B.¹
隶属关系:
1. A.E. Favorskii Irkutsk Institute of Chemistry
期: 卷 89, 编号 1 (2019)
页面: 59-62
栏目: Article
URL: https://journals.rcsi.science/1070-3632/article/view/222700
DOI: https://doi.org/10.1134/S1070363219010109
ID: 222700

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Oxidative cross-coupling of 4-acetylaminophenol (paracetamol) and its structural isomers (2- and 3-acetylaminophenols) with secondary phosphine chalcogenides at room temperature in the CCl₄–Et₃N system produced O-(acetylamino)phenyl chalcogeneophosphinates in a 80% yield.