β-Elimination in 1,1,1-Trichloro-2,2-bis(4-nitrophenyl)ethane by the Action of Sodium Nitrite in Dipolar Aprotic Solvents
- 作者: Guzov E.1, Kazin V.1, Zhukova A.1
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隶属关系:
- Demidov Yaroslavl State University
- 期: 卷 88, 编号 10 (2018)
- 页面: 2044-2049
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222464
- DOI: https://doi.org/10.1134/S1070363218100031
- ID: 222464
如何引用文章
详细
The kinetics of dehydrochlorination of 1,1,1-trichloro-2,2-bis(4-nitrophenyl)ethane with sodium nitrite in dipolar aprotic solvents have been studied. Quantum chemical simulation of the process has been performed, and its thermodynamic parameters have been determined. The effects of dissociation and solvation on the rate constant have been considered. The reaction mechanism has been identified as E2H.
作者简介
E. Guzov
Demidov Yaroslavl State University
编辑信件的主要联系方式.
Email: e.guzov@uniyar.ac.ru
俄罗斯联邦, ul. Sovetskaya 14, Yaroslavl, 150003
V. Kazin
Demidov Yaroslavl State University
Email: e.guzov@uniyar.ac.ru
俄罗斯联邦, ul. Sovetskaya 14, Yaroslavl, 150003
A. Zhukova
Demidov Yaroslavl State University
Email: e.guzov@uniyar.ac.ru
俄罗斯联邦, ul. Sovetskaya 14, Yaroslavl, 150003
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