β-Elimination in 1,1,1-Trichloro-2,2-bis(4-nitrophenyl)ethane by the Action of Sodium Nitrite in Dipolar Aprotic Solvents
- Autores: Guzov E.1, Kazin V.1, Zhukova A.1
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Afiliações:
- Demidov Yaroslavl State University
- Edição: Volume 88, Nº 10 (2018)
- Páginas: 2044-2049
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222464
- DOI: https://doi.org/10.1134/S1070363218100031
- ID: 222464
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Resumo
The kinetics of dehydrochlorination of 1,1,1-trichloro-2,2-bis(4-nitrophenyl)ethane with sodium nitrite in dipolar aprotic solvents have been studied. Quantum chemical simulation of the process has been performed, and its thermodynamic parameters have been determined. The effects of dissociation and solvation on the rate constant have been considered. The reaction mechanism has been identified as E2H.
Sobre autores
E. Guzov
Demidov Yaroslavl State University
Autor responsável pela correspondência
Email: e.guzov@uniyar.ac.ru
Rússia, ul. Sovetskaya 14, Yaroslavl, 150003
V. Kazin
Demidov Yaroslavl State University
Email: e.guzov@uniyar.ac.ru
Rússia, ul. Sovetskaya 14, Yaroslavl, 150003
A. Zhukova
Demidov Yaroslavl State University
Email: e.guzov@uniyar.ac.ru
Rússia, ul. Sovetskaya 14, Yaroslavl, 150003