Synthesis of Functionalized Tris(2-propoxyphenyl)phosphine Oxides as Precursors of Tripodal Propeller-Shaped Ligands
- 作者: Baulina Т.1, Kudryavtsev I.1, Sykat G.1, Brel’ V.1
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隶属关系:
- Nesmeyanov Institute of Organoelement Compounds
- 期: 卷 88, 编号 9 (2018)
- 页面: 1927-1930
- 栏目: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222433
- DOI: https://doi.org/10.1134/S1070363218090281
- ID: 222433
如何引用文章
详细
A series of precursors of novel tripodal ligands (2-XCH2CH2CH2OC6H4)3PO, where X = AcO, HO, MeSO2O, Br, N3, were synthesized by the alkylation of the starting tris(2-hydroxyphenyl)phosphine oxide with 3-bromopropyl acetate followed by hydrolysis of the resulting triacetate to triol and conversion of the latter to trimesylate. Treratment of the resulting trimesylate with LiBr or NaN3 was used to prepare the corresponding tribromo or triazido derivatives.
作者简介
Т. Baulina
Nesmeyanov Institute of Organoelement Compounds
编辑信件的主要联系方式.
Email: zaq@ineos.ac.ru
俄罗斯联邦, ul. Vavilova 28, Moscow, 119991
I. Kudryavtsev
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
俄罗斯联邦, ul. Vavilova 28, Moscow, 119991
G. Sykat
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
俄罗斯联邦, ul. Vavilova 28, Moscow, 119991
V. Brel’
Nesmeyanov Institute of Organoelement Compounds
Email: zaq@ineos.ac.ru
俄罗斯联邦, ul. Vavilova 28, Moscow, 119991