New Nickel(II) Complexes with Tetradentate Schiff Bases Containing Electron-Acceptor Substituents
- 作者: Kurchavov D.1, Karushev M.2, Timonov A.1
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隶属关系:
- Herzen State Pedagogical University of Russia
- St. Petersburg State University
- 期: 卷 88, 编号 7 (2018)
- 页面: 1553-1555
- 栏目: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/222346
- DOI: https://doi.org/10.1134/S1070363218070332
- ID: 222346
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详细
Complexes [Ni(3-NO2SalEn)] and [Ni(3-NO2SaltmEn)] were synthesized and identified, and polymers based on them were obtained. It was found with the help of voltammetry that the introduction of nitro groups in the complexes shifts their redox activity in the direction of positive potentials; it was shown by in situ quartz microgravimetry and in situ absorption spectroscopy methods that fragments of the polymer complexes under study can undergo reversible two-electron oxidation at the expense of formation of polarons and bipolarons in the ligand surrounding.
作者简介
D. Kurchavov
Herzen State Pedagogical University of Russia
编辑信件的主要联系方式.
Email: innatexz@mail.ru
俄罗斯联邦, nab. reki Moiki 48, St. Petersburg, 191186
M. Karushev
St. Petersburg State University
Email: innatexz@mail.ru
俄罗斯联邦, St. Petersburg
A. Timonov
Herzen State Pedagogical University of Russia
Email: innatexz@mail.ru
俄罗斯联邦, nab. reki Moiki 48, St. Petersburg, 191186
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