Self-Assembly in the Systems MX 2 –Nicotinic Hydrazide–Pyruvic Acid (М = Со, Ni; X = Cl, CH 3 COO)

A. V. Pulya; I. I. Seifullina; L. S. Skorokhod; V. G. Vlasenko; A. L. Trigub; S. I. Levchenkov

doi:10.1134/S1070363218070162

Self-Assembly in the Systems MX₂–Nicotinic Hydrazide–Pyruvic Acid (М = Со, Ni; X = Cl, CH₃COO)

作者: Pulya A.¹, Seifullina I.¹, Skorokhod L.¹, Vlasenko V.², Trigub A.³, Levchenkov S.⁴
隶属关系:
1. I.I. Mechnikov National University
2. Research Institute of Physics
3. National Research Center “Kurchatov Institute,”
4. Southern Scientific Center of the Russian Academy of Sciences
期: 卷 88, 编号 7 (2018)
页面: 1451-1455
栏目: Article
URL: https://journals.rcsi.science/1070-3632/article/view/222320
DOI: https://doi.org/10.1134/S1070363218070162
ID: 222320

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In the course of self-assembly in the systems MX₂–nicotinic hydrazide (HN)–pyruvic acid, where М = Co, Ni; X = Сl, CH₃COO, complexes of composition: [CoCl(HNРv)(H₂O)₂], [Co(HNРv)₂], [Ni(HIРv)₂] have been synthesized. Local atomic structure of the coordination centers was established by the method of X-ray absorption spectroscopy. Thermal stability, electric conductivity, and magnetic susceptibility of the complexes have been determined.