Features of Sulfonation of Polychlorinated Biphenyl Congeners
- 作者: Plotnikova K.1, Gorbunova T.1, Pervova M.1, Saloutin V.1, Chupakhin O.1
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隶属关系:
- Postovskii Institute of Organic Synthesis, Ural Branch
- 期: 卷 88, 编号 2 (2018)
- 页面: 257-261
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221995
- DOI: https://doi.org/10.1134/S1070363218020111
- ID: 221995
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详细
Sulfonation of polychlorinated biphenyls (PCBs) and their commercial mixture (Trichlorobiphenyl) with oleum has been studied. General sulfonation patterns have been revealed for PCB congeners having no substituents in the ortho positions. The sulfonation of PCBs with chlorine atoms in only one aromatic ring gives exclusively the corresponding polychlorobiphenylmonosulfonic acids. The sulfonation of PCBs with chlorine atoms in both aromatic rings is accompanied by side formation of polychlorodibenzothiophene S,S-dioxides.
作者简介
K. Plotnikova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pervova@ios.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
T. Gorbunova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pervova@ios.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
M. Pervova
Postovskii Institute of Organic Synthesis, Ural Branch
编辑信件的主要联系方式.
Email: pervova@ios.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
V. Saloutin
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pervova@ios.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
O. Chupakhin
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pervova@ios.uran.ru
俄罗斯联邦, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137