Features of Sulfonation of Polychlorinated Biphenyl Congeners
- Autores: Plotnikova K.1, Gorbunova T.1, Pervova M.1, Saloutin V.1, Chupakhin O.1
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Afiliações:
- Postovskii Institute of Organic Synthesis, Ural Branch
- Edição: Volume 88, Nº 2 (2018)
- Páginas: 257-261
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221995
- DOI: https://doi.org/10.1134/S1070363218020111
- ID: 221995
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Resumo
Sulfonation of polychlorinated biphenyls (PCBs) and their commercial mixture (Trichlorobiphenyl) with oleum has been studied. General sulfonation patterns have been revealed for PCB congeners having no substituents in the ortho positions. The sulfonation of PCBs with chlorine atoms in only one aromatic ring gives exclusively the corresponding polychlorobiphenylmonosulfonic acids. The sulfonation of PCBs with chlorine atoms in both aromatic rings is accompanied by side formation of polychlorodibenzothiophene S,S-dioxides.
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Sobre autores
K. Plotnikova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pervova@ios.uran.ru
Rússia, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
T. Gorbunova
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pervova@ios.uran.ru
Rússia, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
M. Pervova
Postovskii Institute of Organic Synthesis, Ural Branch
Autor responsável pela correspondência
Email: pervova@ios.uran.ru
Rússia, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
V. Saloutin
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pervova@ios.uran.ru
Rússia, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137
O. Chupakhin
Postovskii Institute of Organic Synthesis, Ural Branch
Email: pervova@ios.uran.ru
Rússia, ul. S. Kovalevskoi/Akademicheskaya 22/20, Yekaterinburg, 620137