Mechanism of Protodephenylation of 1,3-Silaheterocyclohexanes. Effect of Heteroatom
- 作者: Kirpichenko S.1, Albanov A.1, Shainyan B.1
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隶属关系:
- A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
- 期: 卷 88, 编号 1 (2018)
- 页面: 96-102
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221954
- DOI: https://doi.org/10.1134/S1070363218010152
- ID: 221954
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详细
The mechanism of electrophilic cleavage of the Si–Ph bond in 1,3-silaheterocyclohexanes is investigated. 3-Aryl-3-silatetrahydropyrans are shown to be less prone to the cleavage of the Si–Ph bond under the action of trifluromethanesulfonic acid than the corresponding 3-silathianes or silacyclohexanes. The effect of heteroatom (N, O, S) in the ring on the functionalization at the silicon atom in 1,3-silaheterocyclohexanes was studied experimentally by the method of NMR spectroscopy and theoretically by DFT calculations and the mechanism was suggested of dephenylation as a function of the nature of heteroatom.
作者简介
S. Kirpichenko
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: bagrat@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
A. Albanov
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
Email: bagrat@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
B. Shainyan
A.E. Favorskii Irkutsk Institute of Chemistry, Siberian Branch
编辑信件的主要联系方式.
Email: bagrat@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo 1, Irkutsk, 664033
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