Derivatives of furyl(diethoxyphosphoryl)acetic aldehyde in Wittig reaction
- 作者: Pevzner L.1
-
隶属关系:
- St. Petersburg State Institute of Technology (Technical University)
- 期: 卷 87, 编号 7 (2017)
- 页面: 1516-1526
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220672
- DOI: https://doi.org/10.1134/S107036321707012X
- ID: 220672
如何引用文章
详细
Reactions of furyl(diethoxyphosphoryl)acetic aldehyde containing ester or cyano group in the furan ring with ethoxycarbonylmethylenetriphenylphosphorane has been shown to afford alkyl E-4-(furyl)-4-(diethoxyphosphoryl)but-3(2)-enoates. When treated with potassium tert-butoxide the mixture of alkyl E-4-(3-ethoxycarbonylfur-2-yl)-4-(diethoxyphosphoryl)but-2-enoate and -but-3-enoate gives a potassium salt of CHacid. Its acidifying results in a mixture of starting compounds with a larger amount of -but-3-enoate. Under analogous conditions the mixture of alkyl E-4-(2-ethoxycarbonylfur-3-yl)-4-(diethoxyphosphoryl)but-2-enoate and -but-3-enoate undergoes cyclization to a phosphorylated derivative of alkyl 7-hydroxybenzofuran-6-carboxylate. The cyclization of the mixture of alkyl E-4-(4-ethoxycarbonylfur-3-yl)-4-(diethoxyphosphoryl)but-2-enoate and -but-3-enoate gives analogous derivative of isobenzofuran.
作者简介
L. Pevzner
St. Petersburg State Institute of Technology (Technical University)
编辑信件的主要联系方式.
Email: pevzner_lm@list.ru
俄罗斯联邦, Moskovskii pr. 26, St. Petersburg, 190031
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