Biomimetic complexes of Cd(II), Mn(II), and Zn(II) with 1,1-diaminobutane–Schiff base. EGA/MS study of the thermally induced decomposition
- 作者: Risoluti R.1, Fabiano M.1, Gullifa G.1, Wo L.1, Materazzi S.1
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隶属关系:
- Department of Chemistry
- 期: 卷 87, 编号 3 (2017)
- 页面: 564-568
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218996
- DOI: https://doi.org/10.1134/S107036321703029X
- ID: 218996
如何引用文章
详细
Frequently, in addition to X-ray and spectroscopic approaches, thermal analysis is the method of choice for comprehensive characterization of precipitated metal complexes. However, thermogravimetry itself is not sufficient enough for explaining complex decomposition or releasing steps. For correct elucidation of the decomposition mechanism of biomimetic Cd(II), Mn(II), and Zn(II) complexes with 1,1-diaminobutane–Schiff base, evolved gas analysis by mass spectrometry (EGA/MS) was used to define the thermally induced steps. Those were synthesized and characterized by hyphenated thermogravimetry-mass spectrometry (TG–MS) that allowed to interpret the decomposition steps.
作者简介
R. Risoluti
Department of Chemistry
Email: stefano.materazzi@uniroma1.it
意大利, Aldo Moro Sq. 5, Rome, 00185
M. Fabiano
Department of Chemistry
Email: stefano.materazzi@uniroma1.it
意大利, Aldo Moro Sq. 5, Rome, 00185
G. Gullifa
Department of Chemistry
Email: stefano.materazzi@uniroma1.it
意大利, Aldo Moro Sq. 5, Rome, 00185
L. Wo
Department of Chemistry
Email: stefano.materazzi@uniroma1.it
美国, S. School Street 251, Normal, IL, 61761
S. Materazzi
Department of Chemistry
编辑信件的主要联系方式.
Email: stefano.materazzi@uniroma1.it
意大利, Aldo Moro Sq. 5, Rome, 00185
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