Synthesis and study of complexes of copper(II) and mercury(II) with triaryl- and diarylalkylarsine oxides
- 作者: Kikashvili M.1, Rusiya M.2, Davitaya T.3
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隶属关系:
- Tsereteli Kutaisi State University
- Dzhavakhishvili Tbilisi State University
- Akva Geo
- 期: 卷 87, 编号 2 (2017)
- 页面: 282-285
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218362
- DOI: https://doi.org/10.1134/S1070363217020219
- ID: 218362
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详细
The interaction of copper(II) and mercury(II) nitrates with triaryl- and diarylalkylarsine oxides has been studied. The reactions in aqueous-alcoholic solution have yielded [M(OAsPh3)4](NO3)2 and [M(OAsRAr2)4](NO3)2 cationic complexes [М = Cu(II) or Hg(II), Ar = Ph, 3-МеC6H4, or 4-МеC6H4, R = Et, Pr, i-Pr, Bu, or i-Bu]. Composition and structure of the products have been elucidated by a set of chemical and physico-chemical methods. IR spectroscopy data have revealed that the bond between the ligand and the metal ion is formed via the oxygen atom of arsenyl group.
作者简介
M. Kikashvili
Tsereteli Kutaisi State University
编辑信件的主要联系方式.
Email: manuchar.kikalishvili@mail.ru
格鲁吉亚, ul. Tsaritsy Tamar 53, Kutaisi
M. Rusiya
Dzhavakhishvili Tbilisi State University
Email: manuchar.kikalishvili@mail.ru
格鲁吉亚, Tbilisi
T. Davitaya
Akva Geo
Email: manuchar.kikalishvili@mail.ru
格鲁吉亚, Mtskheta