Email this article Synthesis and study of complexes of copper(II) and mercury(II) with triaryl- and diarylalkylarsine oxides
- Authors: Kikashvili M.I.1, Rusiya M.S.2, Davitaya T.N.3
-
Affiliations:
- Tsereteli Kutaisi State University
- Dzhavakhishvili Tbilisi State University
- Akva Geo
- Issue: Vol 87, No 2 (2017)
- Pages: 282-285
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218362
- DOI: https://doi.org/10.1134/S1070363217020219
- ID: 218362
Cite item
Open Access
Access granted
Subscription Access
Abstract
The interaction of copper(II) and mercury(II) nitrates with triaryl- and diarylalkylarsine oxides has been studied. The reactions in aqueous-alcoholic solution have yielded [M(OAsPh3)4](NO3)2 and [M(OAsRAr2)4](NO3)2 cationic complexes [М = Cu(II) or Hg(II), Ar = Ph, 3-МеC6H4, or 4-МеC6H4, R = Et, Pr, i-Pr, Bu, or i-Bu]. Composition and structure of the products have been elucidated by a set of chemical and physico-chemical methods. IR spectroscopy data have revealed that the bond between the ligand and the metal ion is formed via the oxygen atom of arsenyl group.
About the authors
M. I. Kikashvili
Tsereteli Kutaisi State University
Author for correspondence.
Email: manuchar.kikalishvili@mail.ru
Georgia, ul. Tsaritsy Tamar 53, Kutaisi
M. Sh. Rusiya
Dzhavakhishvili Tbilisi State University
Email: manuchar.kikalishvili@mail.ru
Georgia, Tbilisi
T. N. Davitaya
Akva Geo
Email: manuchar.kikalishvili@mail.ru
Georgia, Mtskheta
