电邮这篇文章 Solvent-specific reduction of Na2PtI6 in acetone
- 作者: Khazipov O.1, Merzlikina M.2, Nikytenko D.2, Khomutova E.2, Krasnyakova T.2,3, Mitchenko S.1,2
-
隶属关系:
- Platov Southern-Russian State Polytechnic University
- Litvinenko Institute of Physical Organic and Coal Chemistry
- Shevchenko Lugansk State University
- 期: 卷 87, 编号 1 (2017)
- 页面: 128-131
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/217995
- DOI: https://doi.org/10.1134/S1070363217010200
- ID: 217995
如何引用文章
开放存取
##reader.subscriptionAccessGranted##
订阅存取
详细
Oxidation state of iodide complexes of PtII and PtIV in large excess of NaI with respect to platinum in water and acetone solution has been determined by means of 195Pt NMR spectroscopy. In acetone, iodide complexes of PtIV are almost quantitatively reduced into PtII, and iodine is bound in a poorly soluble polymeric complex with sodium iodide and acetone. Iodometric titration has revealed the formation of equivalent amount of iodine. Reduction of platinum has not been observed in aqueous medium.
作者简介
O. Khazipov
Platov Southern-Russian State Polytechnic University
Email: samit_RPt@mail.ru
俄罗斯联邦, ul. Prosveshcheniya 132, Novocherkassk, 346428
M. Merzlikina
Litvinenko Institute of Physical Organic and Coal Chemistry
Email: samit_RPt@mail.ru
乌克兰, Donetsk
D. Nikytenko
Litvinenko Institute of Physical Organic and Coal Chemistry
Email: samit_RPt@mail.ru
乌克兰, Donetsk
E. Khomutova
Litvinenko Institute of Physical Organic and Coal Chemistry
Email: samit_RPt@mail.ru
乌克兰, Donetsk
T. Krasnyakova
Litvinenko Institute of Physical Organic and Coal Chemistry; Shevchenko Lugansk State University
Email: samit_RPt@mail.ru
乌克兰, Donetsk; Lugansk
S. Mitchenko
Platov Southern-Russian State Polytechnic University; Litvinenko Institute of Physical Organic and Coal Chemistry
编辑信件的主要联系方式.
Email: samit_RPt@mail.ru
俄罗斯联邦, ul. Prosveshcheniya 132, Novocherkassk, 346428; Donetsk
