电邮这篇文章 Oligonucleotide cross-linking with copper ions. Spectral and quantum chemical study
- 作者: Bachurin S.1, Faleeva T.2,3, Kletskii M.4, Burov O.4, Askalepova O.4, Kornienko I.3,5
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隶属关系:
- Rostov State Medical University
- Mechnikov North–West State Medical University
- Branch no. 2, Head State Center of Forensic and Criminalistic Examinations
- Southern Federal University
- Academy of Biology and Biotechnologies
- 期: 卷 86, 编号 12 (2016)
- 页面: 2647-2652
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216706
- DOI: https://doi.org/10.1134/S1070363216120124
- ID: 216706
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详细
Copper(II) complexes with synthetic oligonucleotides consisting of repeating adenine–thymine and guanine–cytosine complementary base pairs have been studied by UV spectroscopy and simulated by DFT quantum chemical calculations at the B3LYP/6-311G++(d,p) level of theory with inclusion of solvation (hydration) effects. The obtained data suggest selective interaction of copper(II) ions with guanine–cytosine complementary pairs, followed by DNA cross-linking at those sites.
作者简介
S. Bachurin
Rostov State Medical University
编辑信件的主要联系方式.
Email: bachurin.rostgmu@gmail.com
俄罗斯联邦, per. Nakhichevanskii 29, Rostov-on-Don, 344022
T. Faleeva
Mechnikov North–West State Medical University; Branch no. 2, Head State Center of Forensic and Criminalistic Examinations
Email: bachurin.rostgmu@gmail.com
俄罗斯联邦, ul. Kirochnaya 41, St. Petersburg, 191015; Lermontovskaya ul. 60, Rostov-on-Don, 344000
M. Kletskii
Southern Federal University
Email: bachurin.rostgmu@gmail.com
俄罗斯联邦, ul. Bol’shaya Sadovaya 105/42, Rostov-on-Don, 344006
O. Burov
Southern Federal University
Email: bachurin.rostgmu@gmail.com
俄罗斯联邦, ul. Bol’shaya Sadovaya 105/42, Rostov-on-Don, 344006
O. Askalepova
Southern Federal University
Email: bachurin.rostgmu@gmail.com
俄罗斯联邦, ul. Bol’shaya Sadovaya 105/42, Rostov-on-Don, 344006
I. Kornienko
Branch no. 2, Head State Center of Forensic and Criminalistic Examinations; Academy of Biology and Biotechnologies
Email: bachurin.rostgmu@gmail.com
俄罗斯联邦, Lermontovskaya ul. 60, Rostov-on-Don, 344000; pr. Stachki, 194/1, Rostov-on-Don, 344090
