Formation of cage phosphonate via hydrolysis of 2-(5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl)-1,5-dioxo-4-trifluoromethyl-4-ethoxycarbonylbenzo[f]-1,3,2-dioxaphosphepine
- 作者: Mironov V.1,2, Ivkova G.1, Burnaeva L.1, Mironova E.1,2, Krivolapov D.2
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隶属关系:
- Kazan (Volga Region) Federal University
- Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
- 期: 卷 86, 编号 12 (2016)
- 页面: 2636-2640
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/216692
- DOI: https://doi.org/10.1134/S1070363216120100
- ID: 216692
如何引用文章
详细
A new approach to obtaining of caged bicyclic phosphonate, 4-hydroxy-3-trifluoromethyl-3-ethoxycarbonyl-8-(1-phenylhydrazonoethyl)-5,6-benzo-2,7,1-dioxaphosphabicyclo[3.2.11.5]octane, based on hydrolysis of 2,5-dioxobenzo[f]1,3,2-dioxaphosphepine derivative bearing 5-methyl-2-phenyl-2H-1,2,3-diazaphosphol-4-yl substituent at the phosphorus was developed. The hydrolysis process includes elimination of P(II) atom and intramolecular cyclization involving endocyclic carbonyl group of the phosphepine. Structure of the caged phosphonate was established by NMR and XRD methods.
作者简介
V. Mironov
Kazan (Volga Region) Federal University; Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
编辑信件的主要联系方式.
Email: mironov@iopc.ru
俄罗斯联邦, Kazan, Tatarstan; ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
G. Ivkova
Kazan (Volga Region) Federal University
Email: mironov@iopc.ru
俄罗斯联邦, Kazan, Tatarstan
L. Burnaeva
Kazan (Volga Region) Federal University
Email: mironov@iopc.ru
俄罗斯联邦, Kazan, Tatarstan
E. Mironova
Kazan (Volga Region) Federal University; Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: mironov@iopc.ru
俄罗斯联邦, Kazan, Tatarstan; ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088
D. Krivolapov
Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
Email: mironov@iopc.ru
俄罗斯联邦, ul. Akademika Arbuzova 8, Kazan, Tatarstan, 420088