Chloromethyl derivatives of 3-furyl-3-(diethoxyphosphoryl)acrylic acids
- 作者: Pevzner L.1
-
隶属关系:
- St. Petersburg State Institute of Technology (Technical University)
- 期: 卷 86, 编号 8 (2016)
- 页面: 1864-1870
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215948
- DOI: https://doi.org/10.1134/S1070363216080156
- ID: 215948
如何引用文章
详细
Methoxymetyl derivatives of furoylphosphonates react with ethoxymethylenetriphenylphosphoranes to give phosphorylated (methoxymethylfuryl)acrylates. The reaction proceeds stereoselectively: phosphoryl and ester groups at the double bond are always trans-located. Treatment with dichloromethylmethyl ether and catalytic amount of zinc chloride converts the methoxymethyl group in the synthesized compounds into chloromethyl one. The ester group and the double bond are inert under these conditions.
作者简介
L. Pevzner
St. Petersburg State Institute of Technology (Technical University)
编辑信件的主要联系方式.
Email: pevzner_lm@list.ru
俄罗斯联邦, Moskovskii pr. 26, St. Petersburg, 190013
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