Chloromethyl derivatives of 3-furyl-3-(diethoxyphosphoryl)acrylic acids
- Авторлар: Pevzner L.1
-
Мекемелер:
- St. Petersburg State Institute of Technology (Technical University)
- Шығарылым: Том 86, № 8 (2016)
- Беттер: 1864-1870
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215948
- DOI: https://doi.org/10.1134/S1070363216080156
- ID: 215948
Дәйексөз келтіру
Аннотация
Methoxymetyl derivatives of furoylphosphonates react with ethoxymethylenetriphenylphosphoranes to give phosphorylated (methoxymethylfuryl)acrylates. The reaction proceeds stereoselectively: phosphoryl and ester groups at the double bond are always trans-located. Treatment with dichloromethylmethyl ether and catalytic amount of zinc chloride converts the methoxymethyl group in the synthesized compounds into chloromethyl one. The ester group and the double bond are inert under these conditions.
Негізгі сөздер
Авторлар туралы
L. Pevzner
St. Petersburg State Institute of Technology (Technical University)
Хат алмасуға жауапты Автор.
Email: pevzner_lm@list.ru
Ресей, Moskovskii pr. 26, St. Petersburg, 190013
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