Magnetically-recoverable carbonaceous material: An efficient catalyst for the synthesis of 5-hydroxymethylfurfural and 5-ethoxymethylfurfural from carbohydrates
- 作者: Yao Y.1, Gu Z.1, Wang Y.1, Wang H.1, Li W.1
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隶属关系:
- School of Chemical and Material Engineering
- 期: 卷 86, 编号 7 (2016)
- 页面: 1698-1704
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215763
- DOI: https://doi.org/10.1134/S1070363216070276
- ID: 215763
如何引用文章
详细
A novel, magnetically recoverable carbonaceous solid acid Fe3O4@C-SO3H catalyst for the conversion of carbohydrates to 5-ethoxymethylfurfural (EMF) was developed. The effect of the DMSO fraction in the ethanol-DMSO binary solvent on the distribution of the reaction products was investigated. The catalyst showed an excellent activity in the synthesis of EMF from fructose and 5-hydroxymethylfurfural (HMF). 5- Ethoxymethylfurfural was also obtained with a high yield of 64.2% in an ethanol–DMSO solvent system via one-step conversion of fructose. After reaction, the catalyst could be recovered by exposure of the reaction mixture to external magnetic field and reused several times without a loss of catalytic activity.
作者简介
Y. Yao
School of Chemical and Material Engineering
Email: liweiwuxi@126.com
中国, Wuxi, 214122
Z. Gu
School of Chemical and Material Engineering
Email: liweiwuxi@126.com
中国, Wuxi, 214122
Y. Wang
School of Chemical and Material Engineering
Email: liweiwuxi@126.com
中国, Wuxi, 214122
H.-J. Wang
School of Chemical and Material Engineering
编辑信件的主要联系方式.
Email: wanghj329@outlook.com
中国, Wuxi, 214122
W. Li
School of Chemical and Material Engineering
编辑信件的主要联系方式.
Email: liweiwuxi@126.com
中国, Wuxi, 214122