Reaction of trichlorides of phosphono carboxylic acids with acetylacetone, acetoacetic ester, and phenols
- 作者: Ismailov V.1, Yusubov N.1, Sadykhova N.1, Mamedov I.1, Mamedbekova A.1
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隶属关系:
- Baku State University
- 期: 卷 86, 编号 7 (2016)
- 页面: 1630-1632
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/215674
- DOI: https://doi.org/10.1134/S1070363216070161
- ID: 215674
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详细
Reactions of trichloride of phosphono carboxylic acid with β-dicarbonyl compounds proceed at the active methylene group with the formation of the С-acylation product with a small admixture of the product of O-acylation. The C-acylation products undergo intramolecular condensation to form 1,2-oxophosphorines and compounds of the phosphate structure. The condensation of trichlorides with phenols proceeds selectively at the carbonyl carbon atom leading to C-phenyl esters. With more acidic phenols the splitting of the Р–С bond in the substitution product occurs.
作者简介
V. Ismailov
Baku State University
Email: niftali-yusubov@rambler.ru
阿塞拜疆, ul. Z. Khalilova 23, Baku, 1148
N. Yusubov
Baku State University
编辑信件的主要联系方式.
Email: niftali-yusubov@rambler.ru
阿塞拜疆, ul. Z. Khalilova 23, Baku, 1148
N. Sadykhova
Baku State University
Email: niftali-yusubov@rambler.ru
阿塞拜疆, ul. Z. Khalilova 23, Baku, 1148
I. Mamedov
Baku State University
Email: niftali-yusubov@rambler.ru
阿塞拜疆, ul. Z. Khalilova 23, Baku, 1148
A. Mamedbekova
Baku State University
Email: niftali-yusubov@rambler.ru
阿塞拜疆, ul. Z. Khalilova 23, Baku, 1148