New methacrylate-containing derivatives of hydroxyethyl starch
- 作者: Morgacheva A.1, Artyukhov A.1, Flegontov P.1, Zhavoronok E.2, Shtilman M.1, Panov A.2, Mezhuev Y.1
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隶属关系:
- Mendeleev University of Chemical Technology of Russia
- Lomonosov Moscow State University of Fine Chemical Technologies
- 期: 卷 86, 编号 4 (2016)
- 页面: 885-889
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214674
- DOI: https://doi.org/10.1134/S1070363216040204
- ID: 214674
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详细
Modification of hydroxyethyl starch with glycidyl methacrylate in dimethylsulfoxide medium has resulted in the formation of the derivatives containing double C=C bonds capable of producing biocompatible hydrogels via the free-radical cross-linking. Structure of the glycidyl methacrylate derivatives has been elucidated by means of IR, UV, and NMR spectroscopy. Branching of the hydroxyethyl starch chains in the course of the interaction with glycidyl methacrylate has been observed and interpreted; the branching density has been determined. The influence of the substitution degree of the glycidyl methacrylate derivatives of hydroxyethyl starch on its melting point has been demonstrated.
作者简介
A. Morgacheva
Mendeleev University of Chemical Technology of Russia
编辑信件的主要联系方式.
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俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047
A. Artyukhov
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047
P. Flegontov
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047
E. Zhavoronok
Lomonosov Moscow State University of Fine Chemical Technologies
Email: valsorja@mail.ru
俄罗斯联邦, Moscow
M. Shtilman
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047
A. Panov
Lomonosov Moscow State University of Fine Chemical Technologies
Email: valsorja@mail.ru
俄罗斯联邦, Moscow
Ya. Mezhuev
Mendeleev University of Chemical Technology of Russia
Email: valsorja@mail.ru
俄罗斯联邦, Miusskaya pl. 9, Moscow, 125047