Synthesis of 2-(diphenylphosphoryl)phenyl ethers of ethylene glycols and structure of their sodium and potassium complexes
- 作者: Ivanova I.1,2, Polyakova I.1, Baulin V.2,3, Pyatova E.1,2, Krivorot’ko E.2, Tsivadze A.2
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隶属关系:
- Kurnakov Institute of General and Inorganic Chemistry
- Frumkin Institute of Physical Chemistry and Electrochemistry
- Institute of Physiologically Active Compounds
- 期: 卷 86, 编号 4 (2016)
- 页面: 865-875
- 栏目: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214658
- DOI: https://doi.org/10.1134/S1070363216040186
- ID: 214658
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详细
Phase-transfer catalysis and template assembly on sodium and cesium cations were used to prepare 2-(diphenylphosphoryl)phenyl ethers of ethylene glycols Ln with varied number of polyether units (n = 3–8). Previously unknown dinitro and disulfo derivatives of 2-(diphenylphosphoryl)phenyl ethers of di- and triethylene glycols were synthesized. Complexes [NaL4]NCS·C6H6, [NaL4]ClO4, [KL5]NCS, and [KL5]ReO4 were synthesized, and their crystal structure was studied. Structure–stability constant correlations were found for alkali metal complexes with phosphoryl podands Ln and isodentate crown ethers.
作者简介
I. Ivanova
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
编辑信件的主要联系方式.
Email: isivanova@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991; Moscow
I. Polyakova
Kurnakov Institute of General and Inorganic Chemistry
Email: isivanova@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991
V. Baulin
Frumkin Institute of Physical Chemistry and Electrochemistry; Institute of Physiologically Active Compounds
Email: isivanova@mail.ru
俄罗斯联邦, Moscow; Chernogolovka, Moscow oblast
E. Pyatova
Kurnakov Institute of General and Inorganic Chemistry; Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991; Moscow
E. Krivorot’ko
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
俄罗斯联邦, Moscow
A. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry
Email: isivanova@mail.ru
俄罗斯联邦, Moscow