State of molybdenum clusters in solutions: III. Formation enthalpies of intermediate products of stepwise K 2 [Мо 2 (SO 4 ) 4 ] oxidation in 1 M H 2 SO 4  solution

V. D. Khripun; M. A. Krapivin; K. S. Tsyleva; N. G. Sukhodolov; Yu. V. Kondrat’ev

doi:10.1134/S1070363216010023

State of molybdenum clusters in solutions: III. Formation enthalpies of intermediate products of stepwise K₂[Мо₂(SO₄)₄] oxidation in 1 M H₂SO₄ solution

作者: Khripun V.¹, Krapivin M.¹, Tsyleva K.¹, Sukhodolov N.¹, Kondrat’ev Y.¹
隶属关系:
1. St. Petersburg State University
期: 卷 86, 编号 1 (2016)
页面: 5-8
栏目: Article
URL: https://journals.rcsi.science/1070-3632/article/view/213398
DOI: https://doi.org/10.1134/S1070363216010023
ID: 213398

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The enthalpies of stepwise oxidation reactions of the ions [Mo₂(SO₄)₄]^4– → [Mo₂(SO₄)₄]^3– → [Mo₂(SO₄)₄]^2– → [Мо₂(μ-О)₂O₂(Н₂О)₆]^2– → 2(MoO₄)^2–, and also the enthalpies of formation of the binuclear molybdenum complexes K₃[Mo₂(SO₄)₄], K₂[Mo₂(SO₄)₄], and [Мо₂(μ-О)₂O₂(Н₂О)₆]SO₄ in a 1 М sulfuric acid solution at 298.15 K were determined by the calorimetric titration with continuous titrant input.