Synthesis and Structure of Oxygen-Containing Antimony Complexes (Ar2SbO)4(O2)2

Аннотация

Triarylantimony Ar₃Sb (Ar = 4-FC₆H₄, 3-MeC₆H₄) is oxidized by hydrogen peroxide to form tetranuclear complexes [(4-FC₆H₄)₂SbO]₄(O₂)₂ and [(3-MeC₆H₄)₂SbO]₄(O₂)₂ (as a DMSO solvate). The structure of the resulting compounds was examined by single crystal X-ray diffraction analysis.