Features of сhitosan interaction with copper(II) and cobalt(II) tetrasulfophthalocyanines
- Авторы: Lebedeva N.1, Gubarev Y.1, Yurina E.1, Vyugin A.1, Lipatova I.1
-
Учреждения:
- Krestov Institute of Solution Chemistry
- Выпуск: Том 87, № 10 (2017)
- Страницы: 2327-2331
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/221413
- DOI: https://doi.org/10.1134/S1070363217100139
- ID: 221413
Цитировать
Аннотация
The interaction of chitosan with copper(II) and cobalt(II) tetrasulfophthalocyanines is studied by spectral methods. The main parameters of binding of chitosan to anionic metal phthalocyanines are determined by Scatchard analysis. It is found that the formation of the polymer complex is considerably contributed by donor‒acceptor interactions between the coordinately unsaturated metal phthalocyanine and chitosan amino groups. Сhitosan reacts with a monomeric cobalt(II) tetrasulfophthalocyanine, whereas copper(II) tetrasulfophthalocyanine in its complex with chitosan remains in the dimeric state. The reaction centers responsible for the Cu(SO3H)4Pc)2–chitosan and Co(SO3H)4Pc–chitosan complexes are revealed by means of IR spectroscopy.
Ключевые слова
Об авторах
N. Lebedeva
Krestov Institute of Solution Chemistry
Email: yury.gu@gmail.com
Россия, ul. Akademicheskaya 1, Ivanovo, 153040
Yu. Gubarev
Krestov Institute of Solution Chemistry
Автор, ответственный за переписку.
Email: yury.gu@gmail.com
Россия, ul. Akademicheskaya 1, Ivanovo, 153040
E. Yurina
Krestov Institute of Solution Chemistry
Email: yury.gu@gmail.com
Россия, ul. Akademicheskaya 1, Ivanovo, 153040
A. Vyugin
Krestov Institute of Solution Chemistry
Email: yury.gu@gmail.com
Россия, ul. Akademicheskaya 1, Ivanovo, 153040
I. Lipatova
Krestov Institute of Solution Chemistry
Email: yury.gu@gmail.com
Россия, ul. Akademicheskaya 1, Ivanovo, 153040