Disulfide derivatives of thiosemicarbazones of 4-formyl-5-thiopyrazole
- Авторы: Uraev A.1, Korobov M.1, Popov L.2, Aleksandrov G.3, Korshunova E.1, Garnovskii D.4, Burlov A.1
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Учреждения:
- Research Institute of Physical and Organic Chemistry
- Chemical Department
- N. S. Kurnakov Institute of General and Inorganic Chemistry
- Southern Scientific Center
- Выпуск: Том 87, № 2 (2017)
- Страницы: 252-258
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/218263
- DOI: https://doi.org/10.1134/S1070363217020165
- ID: 218263
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Аннотация
The reaction of 4-formyl-5-mercaptopyrazole with thiosemicarbazides in methanol has afforded novel disulfide derivatives of thiosemicarbazones, and their structure has been studied by NMR and IR spectroscopy. X-ray diffraction analysis of [5,5'-dithiobis(4-formyl-3-methyl-1-phenylpyrazole)]-4-allylthio-semicarbazone has shown that it exists as a dimer with two molecules linked via the disulfide S–S bridge between the heterocycles in the crystal.
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Об авторах
A. Uraev
Research Institute of Physical and Organic Chemistry
Автор, ответственный за переписку.
Email: uraevali@yandex.ru
Россия, pr. Stachki 194/2, Rostov-on-Don, 344090
M. Korobov
Research Institute of Physical and Organic Chemistry
Email: uraevali@yandex.ru
Россия, pr. Stachki 194/2, Rostov-on-Don, 344090
L. Popov
Chemical Department
Email: uraevali@yandex.ru
Россия, Rostov-on-Don
G. Aleksandrov
N. S. Kurnakov Institute of General and Inorganic Chemistry
Email: uraevali@yandex.ru
Россия, Moscow
E. Korshunova
Research Institute of Physical and Organic Chemistry
Email: uraevali@yandex.ru
Россия, pr. Stachki 194/2, Rostov-on-Don, 344090
D. Garnovskii
Southern Scientific Center
Email: uraevali@yandex.ru
Россия, Rostov-on-Don
A. Burlov
Research Institute of Physical and Organic Chemistry
Email: uraevali@yandex.ru
Россия, pr. Stachki 194/2, Rostov-on-Don, 344090
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