Synthesis and hydrophosphorylation of π-complexes of dibenzylideneacetone and cyclic conjugated dienones with homocarbonyl and carbonylcyclopentadienyl molybdenum compounds
- Авторы: Kuramshin A.1, Vatsadze S.2, Galkin V.1, Cherkasov R.1
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Учреждения:
- Kazan Federal University
- Faculty of Chemistry, Moscow State University
- Выпуск: Том 86, № 3 (2016)
- Страницы: 645-655
- Раздел: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/214298
- DOI: https://doi.org/10.1134/S1070363216030221
- ID: 214298
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Аннотация
Reactions of dibenzylideneacetone and cyclic cross-conjugated dienones with hexacarbonylmolybdenum(0) and bis[tricarbonyl(cyclopentadienyl)molybdenum(0)] afforded the corresponding complexes with η2-(C=C),η2-(C=O) coordination of the diketone to metal center, regardless of the ligand structure and initial molybdenum compound. The reactivity of the multidentate ligands may change as a result of coordination.
Об авторах
A. Kuramshin
Kazan Federal University
Автор, ответственный за переписку.
Email: fea_naro@mail.ru
Россия, ul. Kremlevskaya 18, KazanTatarstan, 420008
S. Vatsadze
Faculty of Chemistry, Moscow State University
Email: fea_naro@mail.ru
Россия, Moscow, 119991
V. Galkin
Kazan Federal University
Email: fea_naro@mail.ru
Россия, ul. Kremlevskaya 18, KazanTatarstan, 420008
R. Cherkasov
Kazan Federal University
Email: fea_naro@mail.ru
Россия, ul. Kremlevskaya 18, KazanTatarstan, 420008
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