Thermochemistry of Heteroatomic Compounds. Enthalpy of Dissolution and Vaporization of Selected Trimethylsilyl Di- and Tetrathiophosphates
- Autores: Ovchinnikov V.1, Mal’tseva S.1, Kremleva N.1
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Afiliações:
- A.N. Tupolev Kazan National Research Technical University (KAI)
- Edição: Volume 89, Nº 10 (2019)
- Páginas: 2163-2164
- Seção: Letters to the Editor
- URL: https://journals.rcsi.science/1070-3632/article/view/223142
- DOI: https://doi.org/10.1134/S1070363219100293
- ID: 223142
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Resumo
Enthalpy of vaporization (ΔvapH°) of trimethylsilyl esters of dithio- and tetratiophosphoric acids (RX)2P(S)SSiMe3 (X = O, S) have been determined from the experimentally determined enthalpies of their dissolution (ΔdissH°) in n-hexane at 296–298 K and the values of molar refraction (MRD) with correction a for the branching of the carbon substituent according to the equation ΔvapH° = ΔdH°(n-hexane) + 4.39 + 1.05(MRD − α). The obtained vaporization values can be used to calculate the heats of formation of similar, thermally unstable, compounds for experimental calorimetry.
Sobre autores
V. Ovchinnikov
A.N. Tupolev Kazan National Research Technical University (KAI)
Autor responsável pela correspondência
Email: chem_vvo@mail.ru
Rússia, ul. K. Marksa 10, Kazan, 420111
S. Mal’tseva
A.N. Tupolev Kazan National Research Technical University (KAI)
Email: chem_vvo@mail.ru
Rússia, ul. K. Marksa 10, Kazan, 420111
N. Kremleva
A.N. Tupolev Kazan National Research Technical University (KAI)
Email: chem_vvo@mail.ru
Rússia, ul. K. Marksa 10, Kazan, 420111