Enviar artigo por via de e-mail On the Two-Route Mechanism of the Reaction of 1-Alkenes with EtMgX Catalyzed by TaCl5
- Autores: Sultanov R.1, Khafizov F.1, Ozden I.1, Shutov N.1, Sabirov D.2, Dzhemilev U.2
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Afiliações:
- Ufa State Petroleum Technical University
- Institute of Petrochemistry and Catalysis
- Edição: Volume 89, Nº 4 (2019)
- Páginas: 647-652
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222843
- DOI: https://doi.org/10.1134/S1070363219040029
- ID: 222843
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Resumo
The reaction of 1-alkenes with C2D5MgBr in the presence of TaCl5 has been studied. Basing on the distribution of the deuterium label in the alkyl chain of the regioisomeric organomagnesium compounds, a tentative mechanism of their formation as key intermediates of 3-substituted tantalocyclopentanes has been proposed. The energy profiles of the reactions of carbomagnesation and β-reductive magnesaethylation of 1-alkenes have been obtained using the DFT method.
Sobre autores
R. Sultanov
Ufa State Petroleum Technical University
Autor responsável pela correspondência
Email: sultanov55@mail.ru
Rússia, ul. Kosmonavtov 1, Ufa, 450062
F. Khafizov
Ufa State Petroleum Technical University
Email: sultanov55@mail.ru
Rússia, ul. Kosmonavtov 1, Ufa, 450062
I. Ozden
Ufa State Petroleum Technical University
Email: sultanov55@mail.ru
Rússia, ul. Kosmonavtov 1, Ufa, 450062
N. Shutov
Ufa State Petroleum Technical University
Email: sultanov55@mail.ru
Rússia, ul. Kosmonavtov 1, Ufa, 450062
D. Sabirov
Institute of Petrochemistry and Catalysis
Email: sultanov55@mail.ru
Rússia, pr. Oktyabrya 141, Ufa, 450075
U. Dzhemilev
Institute of Petrochemistry and Catalysis
Email: sultanov55@mail.ru
Rússia, pr. Oktyabrya 141, Ufa, 450075
