Synthesis of Mono- and Disaccharide 4-[(ω-Sulfanylalkyl)oxy]benzoylhydrazones as Potential Glycoligands for Noble Metal Nanoparticles
- Autores: Ershov A.1,2, Martynenkov A.1, Lagoda I.3, Yakimansky A.1,4
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Afiliações:
- Institute of Macromolecular Compounds
- St. Petersburg State Institute of Technology
- State Research Testing Institute of Military Medicine
- St. Petersburg State University
- Edição: Volume 89, Nº 2 (2019)
- Páginas: 292-299
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222758
- DOI: https://doi.org/10.1134/S1070363219020208
- ID: 222758
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Resumo
A procedure has been developed for the synthesis of previously unknown aldose 4-[(ω-sulfanylalkyl) oxy]benzoylhydrazones (where alkyl is hexyl or decyl and aldoses are D-glucose, D-galactose, D-maltose, and D-lactose) that a repromising glycoligands for noble metal nanoparticles. According to the 1H and 13C NMR data, 4-[(ω-sulfanylalkyl)oxy]benzoylhydrazones derived from D-glucose, D-maltose, and D-lactose in crystal and in DMSO-d6 solution have exclusively the cyclic pyranose structure (α- and β-anomers). D-Galactose 4-[(ω-sulfanylalkyl)oxy]benzoylhydrazones in DMSO-d6 solution exist as tautomeric mixtures of cyclic pyranose and open-chain acylhydrazone structures.
Sobre autores
A. Ershov
Institute of Macromolecular Compounds; St. Petersburg State Institute of Technology
Autor responsável pela correspondência
Email: ershov305@mail.ru
Rússia, Bol’shoi pr. V.O. 31, St. Petersburg, 199004; Moskovskii pr. 26, St. Petersburg, 190013
A. Martynenkov
Institute of Macromolecular Compounds
Email: ershov305@mail.ru
Rússia, Bol’shoi pr. V.O. 31, St. Petersburg, 199004
I. Lagoda
State Research Testing Institute of Military Medicine
Email: ershov305@mail.ru
Rússia, ul. Lesoparkovaya, 4, St. Petersburg, 195043
A. Yakimansky
Institute of Macromolecular Compounds; St. Petersburg State University
Email: ershov305@mail.ru
Rússia, Bol’shoi pr. V.O. 31, St. Petersburg, 199004; Universitetskaya nab. 7-9, St. Petersburg, 199034