3-Phosphorylated thioazoles


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Resumo

A novel procedure is reported for the synthesis of 3-phosphorylated N,S-heterocyclic systems by regio- and chemoselective reaction of chloroethynylphosphonates with the thio tautomers of various thioazoles. If the initial sulfanyl azole possesses labile protons or basic NR groups, partial or complete loss of chemoselectivity is observed, and the products are the corresponding acyclic 1,2- and 2,2-substituted alkenylphosphonates.

Sobre autores

D. Egorov

St. Petersburg State Institute of Technology

Email: dog_alla@mail.ru
Rússia, Moskovskii pr. 26, St. Petersburg, 190013

Yu. Piterskaya

St. Petersburg State Institute of Technology

Email: dog_alla@mail.ru
Rússia, Moskovskii pr. 26, St. Petersburg, 190013

E. Erkhitueva

St. Petersburg State Institute of Technology; St. Petersburg State University

Email: dog_alla@mail.ru
Rússia, Moskovskii pr. 26, St. Petersburg, 190013; Universitetskii pr. 26, St. Petersburg, 198504

N. Svintsitskaya

St. Petersburg State Institute of Technology

Email: dog_alla@mail.ru
Rússia, Moskovskii pr. 26, St. Petersburg, 190013

A. Dogadina

St. Petersburg State Institute of Technology

Autor responsável pela correspondência
Email: dog_alla@mail.ru
Rússia, Moskovskii pr. 26, St. Petersburg, 190013


Declaração de direitos autorais © Pleiades Publishing, Ltd., 2017

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