Phosphorylation of alkyl methanesulfonates with elemental phosphorus in a strongly basic medium: Synthesis of alkylphosphinic acids

S. I. Verkhoturova; S. N. Arbuzova; T. I. Kazantseva; N. K. Gusarova; B. A. Trofimov

doi:10.1134/S1070363217080370

Phosphorylation of alkyl methanesulfonates with elemental phosphorus in a strongly basic medium: Synthesis of alkylphosphinic acids

Autores: Verkhoturova S.¹, Arbuzova S.¹, Kazantseva T.¹, Gusarova N.¹, Trofimov B.¹
Afiliações:
1. Favorskii Institute of Chemistry, Siberian Branch
Edição: Volume 87, Nº 8 (2017)
Páginas: 1876-1878
Seção: Letters to the Editor
URL: https://journals.rcsi.science/1070-3632/article/view/221175
DOI: https://doi.org/10.1134/S1070363217080370
ID: 221175

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Alkyl methanesulfonates were for the first time introduced in the reaction of direct phosphorylation of electrophiles with elemental phosphorus in strongly basic media to synthesize alkylphosphinic acids in yields of up to 40%.