Halogenation of quaternary phosphonium salts containing prop-1(2)-enyl group
- Autores: Ovakimyan M.1, Gasparyan G.1, Bichakhchyan А.1, Bagratyan R.1, Derdzyan L.1, Tamazyan R.2, Haivazyan А.2
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Afiliações:
- Science and Technology Center of Organic and Pharmaceutical Chemistry
- Center for Molecular Structure Investigation of National Academy of Sciences of Armenia
- Edição: Volume 87, Nº 8 (2017)
- Páginas: 1727-1730
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220984
- DOI: https://doi.org/10.1134/S1070363217080151
- ID: 220984
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Resumo
Bromination of prop-2-enyltributyl- and -triphenylphosphonium bromides affords the products of addition to the double bond. The structure of the triphenylphosphonium adduct was established by X-ray diffraction analysis. The latter is formed also by radical bromination of prop-1-enyltriphenylphosphonium bromide. The chlorination of prop-1- and 2-enyltriphenylphosphonium bromides leads to the formation of 3-chloroprop-1-enyltriphenylphosphonium bromide.
Sobre autores
M. Ovakimyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Autor responsável pela correspondência
Email: marlena.ovakimyan@rambler.ru
Armênia, ave. Azatutyan 26, Yerevan, 0014
G. Gasparyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Email: marlena.ovakimyan@rambler.ru
Armênia, ave. Azatutyan 26, Yerevan, 0014
А. Bichakhchyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Email: marlena.ovakimyan@rambler.ru
Armênia, ave. Azatutyan 26, Yerevan, 0014
R. Bagratyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Email: marlena.ovakimyan@rambler.ru
Armênia, ave. Azatutyan 26, Yerevan, 0014
L. Derdzyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Email: marlena.ovakimyan@rambler.ru
Armênia, ave. Azatutyan 26, Yerevan, 0014
R. Tamazyan
Center for Molecular Structure Investigation of National Academy of Sciences of Armenia
Email: marlena.ovakimyan@rambler.ru
Armênia, Yerevan
А. Haivazyan
Center for Molecular Structure Investigation of National Academy of Sciences of Armenia
Email: marlena.ovakimyan@rambler.ru
Armênia, Yerevan