Halogenation of quaternary phosphonium salts containing prop-1(2)-enyl group
- Authors: Ovakimyan M.Z.1, Gasparyan G.A.1, Bichakhchyan А.S.1, Bagratyan R.R.1, Derdzyan L.V.1, Tamazyan R.А.2, Haivazyan А.G.2
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Affiliations:
- Science and Technology Center of Organic and Pharmaceutical Chemistry
- Center for Molecular Structure Investigation of National Academy of Sciences of Armenia
- Issue: Vol 87, No 8 (2017)
- Pages: 1727-1730
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220984
- DOI: https://doi.org/10.1134/S1070363217080151
- ID: 220984
Cite item
Abstract
Bromination of prop-2-enyltributyl- and -triphenylphosphonium bromides affords the products of addition to the double bond. The structure of the triphenylphosphonium adduct was established by X-ray diffraction analysis. The latter is formed also by radical bromination of prop-1-enyltriphenylphosphonium bromide. The chlorination of prop-1- and 2-enyltriphenylphosphonium bromides leads to the formation of 3-chloroprop-1-enyltriphenylphosphonium bromide.
About the authors
M. Zh. Ovakimyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Author for correspondence.
Email: marlena.ovakimyan@rambler.ru
Armenia, ave. Azatutyan 26, Yerevan, 0014
G. A. Gasparyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Email: marlena.ovakimyan@rambler.ru
Armenia, ave. Azatutyan 26, Yerevan, 0014
А. S. Bichakhchyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Email: marlena.ovakimyan@rambler.ru
Armenia, ave. Azatutyan 26, Yerevan, 0014
R. R. Bagratyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Email: marlena.ovakimyan@rambler.ru
Armenia, ave. Azatutyan 26, Yerevan, 0014
L. V. Derdzyan
Science and Technology Center of Organic and Pharmaceutical Chemistry
Email: marlena.ovakimyan@rambler.ru
Armenia, ave. Azatutyan 26, Yerevan, 0014
R. А. Tamazyan
Center for Molecular Structure Investigation of National Academy of Sciences of Armenia
Email: marlena.ovakimyan@rambler.ru
Armenia, Yerevan
А. G. Haivazyan
Center for Molecular Structure Investigation of National Academy of Sciences of Armenia
Email: marlena.ovakimyan@rambler.ru
Armenia, Yerevan