Enviar artigo por via de e-mail Oxidation of 5-aminouracil with molecular oxygen in aqueous solution in the presence of copper(II) chloride
- Autores: Murinov Y.1, Mishinkin V.1, Akchurina O.1, Grabovskii S.1, Kabal’nova N.1
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Afiliações:
- Ufa Institute of Chemistry
- Edição: Volume 87, Nº 8 (2017)
- Páginas: 1667-1674
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220938
- DOI: https://doi.org/10.1134/S1070363217080047
- ID: 220938
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Resumo
5-Aminouracil was found to form a six-coordinate copper(II) complex in aqueous solution and undergo oxidation to 5,5,6-trihydroxypyrimidine-2,4(1H,3H)-dione in the presence of molecular oxygen. A scheme was proposed for the fixation and activation of molecular oxygen on six-coordinate copper(II) complex with 5-aminouracil. The effect of the ligand structure on the rate of its oxidation with molecular oxygen in aqueous solution in the presence of copper(II) ions was shown.
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Sobre autores
Yu. Murinov
Ufa Institute of Chemistry
Autor responsável pela correspondência
Email: murinov@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
V. Mishinkin
Ufa Institute of Chemistry
Email: murinov@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
O. Akchurina
Ufa Institute of Chemistry
Email: murinov@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
S. Grabovskii
Ufa Institute of Chemistry
Email: murinov@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
N. Kabal’nova
Ufa Institute of Chemistry
Email: murinov@anrb.ru
Rússia, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
