Oxidation of 5-aminouracil with molecular oxygen in aqueous solution in the presence of copper(II) chloride
- Авторлар: Murinov Y.1, Mishinkin V.1, Akchurina O.1, Grabovskii S.1, Kabal’nova N.1
-
Мекемелер:
- Ufa Institute of Chemistry
- Шығарылым: Том 87, № 8 (2017)
- Беттер: 1667-1674
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220938
- DOI: https://doi.org/10.1134/S1070363217080047
- ID: 220938
Дәйексөз келтіру
Аннотация
5-Aminouracil was found to form a six-coordinate copper(II) complex in aqueous solution and undergo oxidation to 5,5,6-trihydroxypyrimidine-2,4(1H,3H)-dione in the presence of molecular oxygen. A scheme was proposed for the fixation and activation of molecular oxygen on six-coordinate copper(II) complex with 5-aminouracil. The effect of the ligand structure on the rate of its oxidation with molecular oxygen in aqueous solution in the presence of copper(II) ions was shown.
Негізгі сөздер
Авторлар туралы
Yu. Murinov
Ufa Institute of Chemistry
Хат алмасуға жауапты Автор.
Email: murinov@anrb.ru
Ресей, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
V. Mishinkin
Ufa Institute of Chemistry
Email: murinov@anrb.ru
Ресей, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
O. Akchurina
Ufa Institute of Chemistry
Email: murinov@anrb.ru
Ресей, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
S. Grabovskii
Ufa Institute of Chemistry
Email: murinov@anrb.ru
Ресей, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054
N. Kabal’nova
Ufa Institute of Chemistry
Email: murinov@anrb.ru
Ресей, pr. Oktyabrya 71, Ufa, Bashkortostan, 450054