Addition of butanethiol to alkyl 3-furyl-3-(diethoxyphosphoryl)acrylates
- Autores: Pevzner L.1
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Afiliações:
- St. Petersburg State Institute of Technology
- Edição: Volume 87, Nº 6 (2017)
- Páginas: 1148-1160
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/220151
- DOI: https://doi.org/10.1134/S1070363217060081
- ID: 220151
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Resumo
By an example of butanethiol the addition of mercaptanes in the presence of bases to alkyl 3-furyl-3-(diethoxyphosphoryl)acrylic acids having methyl, methoxymethyl, or diethoxyphosphorylmethyl substituent in the furan ring was studied. It was shown that in the majority of cases alkyl 2-(butylthio)propionate was the main product, and 3-(butylthio)propionate was the minor one. Ethyl 3-(4-methylfur-3-yl)-3-(diethoxyphosphoryl) acrylate affords these two substances in equal quantities. In the case of ethyl 3-(4-methoxymethyl-5-methylfur-2-yl)-3-(diethoxyphosphoryl)acrylate only 3-(butylthio)propionate is formed.
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Sobre autores
L. Pevzner
St. Petersburg State Institute of Technology
Autor responsável pela correspondência
Email: pevzner_lm@list.ru
Rússia, Moskovskii pr. 26, St. Petersburg, 190013