Enviar artigo por via de e-mail Hydroalumination of terminal β-acetylene alcohols with lithium aluminum hydride
- Autores: Garibyan O.1, Makaryan G.1, Ogannisyan M.1, Chobanyan Z.1
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Afiliações:
- Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
- Edição: Volume 86, Nº 2 (2016)
- Páginas: 267-272
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213690
- DOI: https://doi.org/10.1134/S1070363216020109
- ID: 213690
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Resumo
Hydrogenation of terminal β-acetylene alcohols with lithium aluminum hydride in THF has afforded homoallylic alcohols. Decomposition of the intermediate organoaluminum complex with deuterated water, iodine, or pyridinium dibromide has evidenced about the non-regioselective hydride attack at the triple bond.
Sobre autores
O. Garibyan
Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Autor responsável pela correspondência
Email: hgaribyan@mail.ru
Armênia, ave. Azatutyan 26, Yerevan, 0014
G. Makaryan
Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: hgaribyan@mail.ru
Armênia, ave. Azatutyan 26, Yerevan, 0014
M. Ogannisyan
Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: hgaribyan@mail.ru
Armênia, ave. Azatutyan 26, Yerevan, 0014
Zh. Chobanyan
Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: hgaribyan@mail.ru
Armênia, ave. Azatutyan 26, Yerevan, 0014
