Email this article Hydroalumination of terminal β-acetylene alcohols with lithium aluminum hydride
- Authors: Garibyan O.A.1, Makaryan G.M.1, Ogannisyan M.R.1, Chobanyan Z.A.1
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Affiliations:
- Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
- Issue: Vol 86, No 2 (2016)
- Pages: 267-272
- Section: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213690
- DOI: https://doi.org/10.1134/S1070363216020109
- ID: 213690
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Abstract
Hydrogenation of terminal β-acetylene alcohols with lithium aluminum hydride in THF has afforded homoallylic alcohols. Decomposition of the intermediate organoaluminum complex with deuterated water, iodine, or pyridinium dibromide has evidenced about the non-regioselective hydride attack at the triple bond.
About the authors
O. A. Garibyan
Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Author for correspondence.
Email: hgaribyan@mail.ru
Armenia, ave. Azatutyan 26, Yerevan, 0014
G. M. Makaryan
Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: hgaribyan@mail.ru
Armenia, ave. Azatutyan 26, Yerevan, 0014
M. R. Ogannisyan
Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: hgaribyan@mail.ru
Armenia, ave. Azatutyan 26, Yerevan, 0014
Zh. A. Chobanyan
Institute of Fine Organic Chemistry, Scientific Technological Center of Organic and Pharmaceutical Chemistry
Email: hgaribyan@mail.ru
Armenia, ave. Azatutyan 26, Yerevan, 0014
