Study of the reaction of 3,6-di-tert-butyl-о-benzoquinone with organozinc and organocadmium compounds
- Autores: Kurskii Y.1, Druzhkov N.1, Egorochkin A.1, Abakumov G.1
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Afiliações:
- Razuvaev Institute of Organometallic Chemistry
- Edição: Volume 86, Nº 1 (2016)
- Páginas: 37-42
- Seção: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/213408
- DOI: https://doi.org/10.1134/S1070363216010072
- ID: 213408
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Resumo
The effect of substituents in the reactions of 3,6-di-tert-butyl-о-benzoquinone with organozinc and organocadmium compounds, leading to three types of products: 3-alkyl-6-tert-butyl-о-benzoquinones, 4-alkyl-3,6-di-tert-butyl-о-benzoquinones, and 2-alkoxy-(or 2-phenoxy)-3,6-di-tert-butylphenols. Correlation analysis gave evidence to show that the first- and second-type products are formed by nucleophilic 1,2- and 1,4-addition, while substituted phenols result from single-electron transfer.
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Sobre autores
Yu. Kurskii
Razuvaev Institute of Organometallic Chemistry
Autor responsável pela correspondência
Email: kursk@iomc.ras.ru
Rússia, ul. Tropinina 49, Nizhny Novgorod, 603950
N. Druzhkov
Razuvaev Institute of Organometallic Chemistry
Email: kursk@iomc.ras.ru
Rússia, ul. Tropinina 49, Nizhny Novgorod, 603950
A. Egorochkin
Razuvaev Institute of Organometallic Chemistry
Email: kursk@iomc.ras.ru
Rússia, ul. Tropinina 49, Nizhny Novgorod, 603950
G. Abakumov
Razuvaev Institute of Organometallic Chemistry
Email: kursk@iomc.ras.ru
Rússia, ul. Tropinina 49, Nizhny Novgorod, 603950
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