Some Aspects of Metal Exchange Between Cadmium Porhyrinate Octa-(4-bromophenyl)porphyrin and Cobalt Chloride in Organic Solvents
- Авторлар: Zvezdina S.1, Chizhova N.1, Mamardashvili N.1
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Мекемелер:
- G.A. Krestov Institute of Solution Chemistry
- Шығарылым: Том 88, № 9 (2018)
- Беттер: 1996-1999
- Бөлім: Article
- URL: https://journals.rcsi.science/1070-3632/article/view/222453
- DOI: https://doi.org/10.1134/S1070363218090426
- ID: 222453
Дәйексөз келтіру
Аннотация
The metal-exchange reaction between Cd(II) octa-(4-bromophenyl)porphyrinate and cobalt chloride in DMF and DMSO was studied by UV-Vis spectroscopy. The kinetic parameters of the metal-exchange reaction were calculated. A possible mechanism of the reaction was established. An effect of the nature of the solvent and metal salt on the reaction rate was revealed. Comparative analysis of the apparent rate constants of the metal exchange reaction between CoCl2 and Cd(II) octa-(4-bromophenyl)porphyrinates and Cd(II) octa-(4-bromophenyl)tetraazaporphyrinate in DMF and DMSO was performed.
Авторлар туралы
S. Zvezdina
G.A. Krestov Institute of Solution Chemistry
Хат алмасуға жауапты Автор.
Email: svvr@isc-ras.ru
Ресей, ul. Akademicheskaya 1, Ivanovo, 153045
N. Chizhova
G.A. Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
Ресей, ul. Akademicheskaya 1, Ivanovo, 153045
N. Mamardashvili
G.A. Krestov Institute of Solution Chemistry
Email: svvr@isc-ras.ru
Ресей, ul. Akademicheskaya 1, Ivanovo, 153045
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